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1 article(s) from Schröder, Martin

Tuning the interactions between electron spins in fullerene-based triad systems

Maria A. Lebedeva,
Thomas W. Chamberlain,
E. Stephen Davies,
Bradley E. Thomas,
Martin Schröder and
Andrei N. Khlobystov

Beilstein J. Org. Chem. 2014, 10, 332–343, doi:10.3762/bjoc.10.31

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Figure 1: Structures of triads 1–6 and precursor molecules 7–8 used for the synthesis of the asymmetric syste...

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Scheme 1: The one-step synthetic procedure towards the oxalate-bridged fullerene triads 4 and 6.

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Scheme 2: Attempted synthetic pathway towards the formation of the C₆₀–C₇₀ oxalate bridged fullerene triad al...

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Scheme 3: Synthetic pathway to the asymmetric fullerene triad 5 allowing introduction of the fullerene cages ...

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Figure 2: Cyclic voltammograms of the terephthalate bridged triads 1–3 (left) and oxalate bridged triads 4–6 ...

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Figure 3: Fluid solution EPR spectra recorded at 297 K for the two electron reduced species of compounds 1 an...

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Figure 4: Frozen solution EPR spectra of triads 4²⁻ (a) and 1²⁻ (c), prepared by two electron reduction of 4 ...

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Published 05 Feb 2014

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